Energy Band-gap Calculation of d-Ta2O5 Using sX-LDA and B3LYP Methods

The energy band-gap and related factors of tantalum pentoxide with hexagonal phase were investigated using hybrid functional B3 LYP and s X-LDA methods. The results showed that both s X-LDA and B3 LYP techniques reveal the indirect semiconductor nature of δ-Ta2O5, whereas the obtained value of energy band-gap is much higher than previous theoretical reports but closer to the experimental data. The optical bandgap of δ-Ta2O5 is expected to originate from the O 2p→Ta 5d transition which may benefit from the d-s-p hybridization.     

基于传递矩阵算法的裂隙注浆扩散机制研究

在裂隙岩体注浆工程中,由注浆压力引起的裂隙位移对注浆扩散过程影响显著。为研究浆体在裂隙岩体流动时浆液的扩散规律,克服以往假设裂隙无开度变化且仅在单一裂隙内考虑浆液扩散的情况,将传递矩阵算法引入宾汉流体本构方程,利用传递矩阵求解任意位置处的裂隙位移,同时建立考虑浆液在岩体间劈裂注浆的简化裂隙岩体模型通过加设阻力来模拟浆液在岩体内扩散的能量耗损,从而在平板裂隙条件下可以完整准确描述浆液在裂隙中及岩体间连续扩散的过程,建立了基于传递矩阵法的裂隙岩体注浆模型。应用有限元软件ＣＯＭＳＯＬ分别建立单裂隙、多裂隙注浆模型对上述理论模型进行对比验证。     

基于双重故障模式的微型电网电压自愈控制方法研究

针对故障干扰容易造成电网负荷损失的问题与负荷裕度较小且分布不均等问题,提出双重故障模式的微型电网电压自愈控制系统等效处理微型电网运行模式。通过有向图路径矩阵及其关联矩阵确定供电路径计算传输功率,构建网络故障关联与拓扑矩阵然后对双重故障形成关联,实现负荷裕度损失较小的条件下进行微型电网电压自愈控制的目的。实验表明,故障检测过程中负荷裕度提升值较高且分布均匀,紧急负荷补偿能力较高,故障定位下的微型电网负荷性能得到提升且具有良好的稳定性。     

一种描述磁流变弹性体滞回特性的分数阶导数改进Bouc?Wen模型

为了准确表征大范围应变幅值、激励频率和磁场下磁流变弹性体(Magnetorheological elastomer, MRE)的力学行为,本文引入黏弹性分数阶导数,提出一种描述磁流变弹性体滞回特性的分数阶导数改进Bouc?Wen模型。分析了各向同性与异性MRE的微观形貌特征,对MRE进行了性能试验,研究发现,MRE的储能和损耗模量随着应变幅值(0～100%)增大先不变后减小,随着频率(0～100 Hz)增大而增大,随着磁场(0～545 mT)增大而增大。在此基础上,基于分数阶导数提出改进Bouc?Wen模型,在Simulink软件中建立仿真模型,利用Oustaloup滤波器算法对分数阶导数项近似计算,对比分析验证了改进模型的有效性,各工况下仿真数据和试验数据的吻合度均高于98%。结果表明:改进Bouc?Wen模型能准确地模拟MRE应力应变滞回曲线,拟合精度较Bouc?Wen模型明显提升,改进模型在较宽的应变幅值、频率和磁场范围内是准确有效的,为实现MRE的工程应用打下基础。      

地铁隧道局部冻结方案设计及参数分析

为了研究地铁隧道冻结工程中的冻结管形式选择和地表冻胀量控制问题,依托广州市轨道交通13号线北延线机场区间隧道冻结工程,采用了室内试验、现场实测、数值计算的方法,对保温工艺、形式和冻结孔间距、保温段长度、冻结时间对地表冻胀量的影响进行了研究。研究结果表明:冻结管采用保温材料隔热方式可有效实现局部冻结,但施工时保温材料需进行防水处理,防止因地下水进入保温材料造成导热系数增加;地表冻胀量与保温长度呈线性反比关系,且随孔间距的增大比例系数逐步减小,随冻结时间延长增大。根据实测数据、计算得到了适用于本工程工况的冻胀量预测公式;结合工程现场条件,分析了制冷能耗和冻胀量与孔间距的关系,提出了在保证地表冻胀量的前提下,尽量减少冻结孔间距达到缩减工期、能耗的目的。     

Effect of friction reclaimed materials of waste brake-shoe on basic performance of mortar

Discarded train brake shoes mainly consist of steel-backed friction material. To be better reutilized, its essential features and its interaction in cement-based material need to be studied. Consequently, particle size analysis, SEM, IR and TGA were used to investigate two types of waste brake shoes, i e, mechanical grinding friction reclaimed material of waste brake-shoe (G-FRMWBS) and pyrolysis-friction reclaimed materials of waste brake-shoe (P-FRMWBS). The latter exhibited less organic content, larger range of particle size distribution and smaller medium particle diameter. Both types contained inorganic particles of spherical and irregular shapes, striped with steel fiber. Upon isometric substituting fine aggregates, G-FRMWBS lifted the strength of mortar effectively that was increased by 16.6% and 17.5% when the replacing rate was 5%; the value went up to 19.2% and 19.2% when the replacing rate was 10%. Moreover, inclusion of FRMWBS enhanced the chloride penetration resistance, and optimized the pore characteristic and ITZ (interfacial transition zone) as well.     

波浪循环荷载作用下滨海软土水平向动力特性试验研究

为研究海上风电桩基在波浪荷载作用下,产生水平向循环荷载对桩基周围土体动力特性的影响,以唐山地区滨海软土为研究对象,通过室内动三轴试验,研究不同围压、动应力幅值和振动次数条件下对软土水平向动力特性的影响。结果表明:软土水平向动强度随围压增加而增加,随振动次数增加而减小;动应力幅值增大,破坏振次减小;水平向动应变ε_d随振动次数增加变大,且动应力幅值越大,增速越明显,变化规律遵循Monismith模型;动应力幅值改变时,软土水平向动模量变化明显,当围压减小,动弹性模量减小;曹妃甸软土水平向间具有明显的结构性,不同围压条件下,随动应力幅值增加动阻尼比均表现增大趋势。     

战场宽带数据链分布式虚拟骨干网的构建

宽带数据链作为现代战场的神经网络和信息传输通道,必须采用分布式虚拟骨干网构建算法才能适应战场环境的大容量、多样性数据传输和时变性网络结构。针对这一问题,提出了一种分布式虚拟骨干网构建算法-DCDS算法。该算法中,每个节点只需获取其两跳范围内的邻居节点信息,无需获知全网拓扑信息。理论分析和仿真表明,相比Wu等2种经典算法,DCDS算法具有更小的消息开销和虚拟骨干网构建规模,更适合于大数据量、高动态的战场宽带数据链网络。     

地铁直流牵引供电系统振荡机理分析

地铁直流牵引供电系统低频振荡电流是导致DDL保护误动的主要原因。从系统分析的角度,建立了计及电动车辆影响的直流牵引供电系统电磁暂态模型及系统振荡时的非线性二阶动态模型。在唯一平衡点邻域内,利用李亚普诺夫间接法将非线性动态系统转换为线性系统后,确定出系统振荡的结构条件。实例计算和仿真表明,牵引变流器和牵引电机的等效负电阻是系统不稳定的主要电气参量,系统振荡频率主要取决于车载滤波电容与滤波电感,且系统仿真波形在众多特征上与实际记录的电流波形基本一致。     

Phase Equilibrium studies in the system “FeO”–SiO2–Al2O3–CaO–MgO at 1200 °C and Po2 10-8atm

Iron oxides and silica are the major components of copper smelting slag. The oxides of aluminum, calcium and magnesium are also present in the slag that is introduced through copper concentrate, flux and refractories. Liquidus temperatures of the copper smelting slags are usually controlled by Fe/SiO₂. The concentrations of Al₂O₃, CaO and MgO, and FeO/Fe₂O₃ in the slag can also affect the liquidus temperatures where FeO/Fe₂O₃ is a function of oxygen partial pressure. High temperature equilibration under controlled oxygen partial pressure followed by quenching and electron probe microanalysis were used to determine the compositions of the liquid and solid phases at 1200 °C and Po₂ 10^-8 atm. The experimental results are presented in the forms of pseudo-ternary sections “FeO”-CaO-SiO₂ at fixed 2, 4 and 6 wt pct MgO, and 2 + 2, 4 + 4 and 6 + 6 wt pct MgO + Al₂O₃. Spinel and tridymite are the major primary phases in the composition range investigated. In addition, CaSiO₃, pyroxene, olivine, and melilite are also present. The isotherms in the spinel and tridymite primary phase fields move towards higher SiO₂ concentration directions with increasing CaO, Al₂O₃, and MgO concentrations. The experimentally determined results are compared with the FactSage calculations.